One year of MAX-DOAS measurements of tropospheric trace gases and aerosols in the suburban area of London

Abstract

<p>Multi-AXis (MAX)-DOAS instruments record spectra of scattered sun light under different elevation angles. From such measurements tropospheric vertical column densities (VCDs) and vertical profiles of different atmospheric trace gases and aerosols can be determined for the lower troposphere. These measurements allow a simultaneous observation of multiple trace gases (e.g. HCHO, CHOCHO, NO<sub>2</sub>, etc.) with the same measurement setup. Since November 2018, a MAX-DOAS instrument is operated at the Bayfordbury Observatory, which is located approximately 30 km north of London. This measurement site is operated by the University of Hertfordshire and equipped with an AERONET station, a LIDAR and multiple instruments to measure meteorological quantities and solar radiation. Depending on the prevailing wind direction the air masses at the measurement site can be dominated by the pollution of London (SE to SW winds) or rather pristine air (northerly winds). Therefore, this measurement site is well suited to study the influence of anthropogenic pollution on the atmospheric composition and chemistry at a rather pristine location in the vicinity of London, a major European capital with 9.8 million inhabitants and 4 major international airports.</p><p>In this study, trace gas and aerosol profiles are retrieved using the MAinz Profile Algorithm MAPA (Beirle et al., 2018) with a focus on tropospheric formaldehyde (HCHO) which plays an important role in tropospheric chemistry. The HCHO results are combined with the results of other trace species such as NO<sub>2</sub>, CHOCHO and aerosols in order to identify different chemical regimes and pollution levels.</p>