One-Step Synthesis of Transition Metal Dichalcogenide Quantum Dots Using Only Alcohol Solvents for Indoor-Light Photocatalytic Antibacterial Activity

Abstract

In this study, we report a one-step direct synthesis of molybdenum disulfide (MoS2) and tungsten disulfide (WS2) quantum dots (QDs) through a solvothermal reaction using only alcohol solvents and efficient Escherichia coli (E. coli) decompositions as photocatalytic antibacterial agents under visible light irradiation. The solvothermal reaction gives the scission of molybdenum–sulfur (Mo–S) and tungsten–sulfur (W–S) bonding during the synthesis of MoS2 and WS2 QDs. Using only alcohol solvent does not require a residue purification process necessary for metal intercalation. As the number of the CH3 groups of alcohol solvents among ethyl, isopropyl, and tert(t)-butyl alcohols increases, the dispersibility of MoS2/WS2 increases. The CH3 groups of alcohols minimize the surface energy, leading to the effective exfoliation and disintegration of the bulk under heat and pressure. The bulky t-butyl alcohol with the highest number of methyl groups shows the highest exfoliation and yield. MoS2 QDs with a lateral size of about 2.5 nm and WS2 QDs of about 10 nm are prepared, exhibiting a strong blue luminescence under 365 nm ultraviolet (UV) light irradiation. Their heights are 0.68–3 and 0.72–5 nm, corresponding to a few layers of MoS2 and WS2, respectively. They offer a highly efficient performance in sterilizing E. coli as the visible-light-driven photocatalyst.

Fast detection of Staphylococcus aureus using thiol-functionalized WS2 quantum dots and Bi2O2Se nanosheets hybrid through a fluorescence recovery mechanism

“…35–39 TMD NSs and QDs have also been investigated in various antibacterial and antifungal activities to kill Gram-positive and negative bacteria, such as E. coli and S. aureus bacteria. 40–44 Due to their excellent properties, 2D WS 2 QDs are also utilized in sensing applications, but their utilization in the detection of bacteria has not yet been explored. 45,46 In the mechanism of FL enhancement based sensing, a fluorescence quencher is required, which absorbs emissions from the probe and quenches the probe's FL emission intensity.…”