Although many routes have been developed that can efficiently improve the electrochemical performance of LiFePO 4 (LFP) cathode for Li ion batteries, few of them meet the urgent industrial requirements: large scale production, low cost and excellent performance. In this work, via a hydrothermal synthetic proceed followed by a high-temperature lithiation, we are able to design porous micro-spherical LFP/Carbon 10 Nanotubes (CNTs) nanocomposite. The efficient combination of the inside CNTs and the outside carbon layer, as well as the porous structure of the LFP/CNT nanocomposite lead to its excellent electrochemical performance. As cathode material for Li ion batteries, the discharge capacity of the nanocomposite can reach 122 mAh/g at 20 C. After 500 cycles, capacity retention of 94.3 % can be reached at 1 C. Because of the facile and easily scale up synthsized method, low cost raw materials and the excellent 15 electrochemical performance, the as-designed LFP/CNT nanocomposite can be expected as a potential cathode candidate for Li ion batteries.