“…As a kind of common industrial material, azo compounds are extensively used as dyes, pigments, drugs, and energetic materials. − While most monoamines can be easily coupled to azo products without worrying much about byproducts, the oxidative coupling of polyamines not only forms multiple intermediates and excessive oxidation byproducts but also may lead to a variety of isomers (Figure A), − thus creating formidable barriers for a simple and low-cost synthesis of aminoazo compounds. Therefore, developing a direct synthetic route for a selective oxidative coupling of polyamines can efficiently increase the construction speed, allowing for easier industrial production, and is thus considered both challenging and rewarding …”