2012
DOI: 10.1007/s12274-012-0233-2
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One-step hydrothermal synthesis of ZnFe2O4 nano-octahedrons as a high capacity anode material for Li-ion batteries

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Cited by 244 publications
(124 citation statements)
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“…It decreases to 790 mA h g -1 for the 50 th cycle, and interestingly, a high reversible specific capacity of 886 mA h g -1 can be achieved after 450 cycles. Similar phenomenon was also observed by previous reports on NiCo 2 O 4 mesoporous microspheres[31], Au nanoparticles decorated NiCo 2 O 4 nanotubes[18], ZnFe 2 O 4 nano-octahedrons[74], which is explain as the drastic structure reorganization accompanied by decomposition and reformation of the electrolyte. The morphology changes of the electrodes after cycling (see in the supporting information,Fig.…”
supporting
confidence: 90%
“…It decreases to 790 mA h g -1 for the 50 th cycle, and interestingly, a high reversible specific capacity of 886 mA h g -1 can be achieved after 450 cycles. Similar phenomenon was also observed by previous reports on NiCo 2 O 4 mesoporous microspheres[31], Au nanoparticles decorated NiCo 2 O 4 nanotubes[18], ZnFe 2 O 4 nano-octahedrons[74], which is explain as the drastic structure reorganization accompanied by decomposition and reformation of the electrolyte. The morphology changes of the electrodes after cycling (see in the supporting information,Fig.…”
supporting
confidence: 90%
“…As shown in Fig. 6c, two major peaks at 711.3 and 724.5 eV and two smaller shakeup satellites are detected, which can be assigned to Fe 2p 3/2 and Fe 2p 1/2 of Fe 3+ [32,36], respectively. The highresolution scan of O 1s of the NiFe 2 O 4 /C hollow spheres exhibits two peaks located at 530.4 eV and 531.8 eV (Fig.…”
Section: Resultsmentioning
confidence: 88%
“…[ 43 ] Remarkably, the initial discharge capacity of the ZZFO SMCs demonstrated here is much larger than those for other composite anodes, such as, Fe 2 O 3 /MnO 2 (≈1480 mA g −1 ), [ 10 ] Co 3 O 4 /Fe 2 O 3 (≈1687 mAh g −1 ), [ 5 ] NiFe 2 O 4 /Fe 2 O 3 (≈1401 mAh g −1 ), [ 8 ] CoO/ CoFe 2 O 4 (≈1285 mAh g −1 ), [ 9 ] ZnO/ZnFe 2 O 4 (≈650 mA g −1 ), [ 14 ] and even other ZnFe 2 O 4 samples (≈1400 mAh g −1 ). [ 44,45 ] The fi rst charge (i.e., de-lithiation) curve of the ZZFO anode illustrates the lithium extraction, in which a stead and smooth voltage increase from 0.01 to 3.00 V, and the overall charging capacity is ≈1371 mAh g −1 . As a consequency, there is an irreversible capacity loss of ≈521 mAh g −1 between the fi rst discharge and charge cycles, accordingly, the initial Coulombic effi ciency (CE) is ≈70%, very close to that of the single ZFO anode (≈72%).…”
Section: Electrochemical Performance Of Hierarchical Mesoporous Zzfo mentioning
confidence: 99%