We report the stackable all-solid-state supercapacitor based on the three dimensional ppy-NiO/RGO-CNT electrodes. The electrode was prepared by growing NiO nanowalls (NWs) on both sides of a freestanding RGO-CNT film with hydrothermal method, followed by being coated with conductive polypyrrole. The double-sided architecture of NiO NWs on carbon-based current collector suggests the novel approach in addressing the issue of low areal capacitance in supercapacitor. Furthermore, conductive polypyrrole renders fast electron transport through the two-dimensional structure of NiO NWs. With our 3Ddesigned electrode, we successfully fabricated the stackable all-solid-state supercapacitor and thus achieved high areal capacitance of 1,948 mF cm -2 . PPy-coated NiO nanowalls were encapsulated with PVA-KOH gel electrolyte, producing a single electrode of all-solid-state supercapacitors. A pair of the electrochemical capacitors exhibited the areal capacitance of 664 mF cm -2 at a current density of 1 mA cm -2 . In this work, we demonstrated a prototype multilayered supercapacitors by stacking 3 pairs of