One-pot synthesis of a novel supramolecular compound based on three kinds of Keggin polyoxoanions PMo12O403− with different coordination modes

Three new inorganic-organic hybrid compounds based on α-Keggin clusters and Ag-organic subunits, [Ag 3 L 4 (H 2 O) 4 ][PMo 12 O 40 ]·3H 2 O (1), [Ag 3 L 4 (H 2 O) 4 ][PW 12 O 40 ]·2H 2 O (2), and [Ag 3 L 6 ][PMo 12 O 40 ] (3) [L = 1-amino-4-(3,5-dimethylpyrazolyl)hydralazine], were synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction. Compounds 1 and 2 are isostructural and contain two kinds of Ag subunits: dinuclear [Ag 2 L 2 (H 2 O) 4 ] 2+ and mononuclear [AgL 2 ] + . The dinuclear Ag clusters are linked by Keggin anions to construct a 1D chain, whereas

show abstract

Three New Keggin‐based Compounds Constructed by a Hydralazine Derivative Ligand: Assembly, Structures, and Properties

Tian

Hou

Sun

et al. 2014

Zeitschrift anorg allge chemie

View full text Add to dashboard Cite

show abstract

Two Keggin polyoxoanion-based hybrids composed of CuI/tbz segments: Syntheses, structures and electrochemical properties

Wang

Peng

Alimaje

et al. 2013

Inorganic Chemistry Communications

View full text Add to dashboard Cite

Assembly of sandwich-type 3-D supramolecular coordination polymers based on hexa-molybdenum chain and {PMo12O40} heteropolyanion

Wan

Wang

et al. 2015

Inorganic Chemistry Communications

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

hi@scite.ai

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

One-pot synthesis of a novel supramolecular compound based on three kinds of Keggin polyoxoanions PMo12O403− with different coordination modes

Cited by 7 publications

References 30 publications

Three New Keggin‐based Compounds Constructed by a Hydralazine Derivative Ligand: Assembly, Structures, and Properties

Three New Keggin‐based Compounds Constructed by a Hydralazine Derivative Ligand: Assembly, Structures, and Properties

Two Keggin polyoxoanion-based hybrids composed of CuI/tbz segments: Syntheses, structures and electrochemical properties

Assembly of sandwich-type 3-D supramolecular coordination polymers based on hexa-molybdenum chain and {PMo12O40} heteropolyanion

Contact Info

Product

Resources

About