One-Pot Synthesis, Circularly Polarized Luminescence, and Controlled Self-Assembly of Janus-Type Miktoarm Star Copolymers
Hui Zou,
Shuyang Zhao,
Qiliang Wu
et al.
Abstract:With the aim of broadening the scope of Janus-type polymers with new functionalities, Janus-type miktoarm star copolymers comprising helical poly(phenyl isocyanide) (PPI) and a vinyl polymer were designed and synthesized via a combination of Pd(II)-initiated isocyanide polymerization and atom transfer radical polymerization (ATRP). A functional βcyclodextrin bearing 7 Pd(II) complexes at one side and 14 bromine groups at the other side ((Pd(II)) 7 -CD-(Br) 14 ) was prepared and used as an initiator for the one… Show more
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