One-pot sequential deoximation and allylation reactions of aldoximes in aqueous solution

Sustainable Generation of Ni(OH)2 Nanoparticles for the Green Synthesis of 5-Substituted 1H-Tetrazoles: A Competent Turn on Fluorescence Sensing of H2O2

“…42,43 Incidentally, several reports are available in the literature regarding the synthesis of tetrazole compounds catalyzed by diverse type of nickel-based NPs. 44−48 Moreover, aldoxime derivatives have captured the attention of synthetic organic chemists during the past few years 49−51 because of their good reactivity and less toxic nature and the fact that they can be prepared very easily. Very recently, Patil, 52 Babu, 53 and Matsugi 54 have reported, respectively, the homogeneous Cu(OAc) 2 , InCl 3 , and DPPA catalyzed synthesis of 5-substituted 1 H -tetrazoles from aldoxime and sodium azide.…”

“…In this context, nickel as a transition metal catalyst, creates a promising center of attraction toward the researchers. Nanoparticles (NPs), having unusually huge surface area and large number of active sites, can efficiently catalyze several organic reactions providing the advantages of high atom economy, mild reaction conditions, simplified isolation of product, easy recovery, and recyclability of the catalysts. − Considering the ongoing attempts and increasing awareness to develop simple, environment-friendly, economic, and profitable synthetic methods, nickel-based NPs can serve as a powerful alternative. , Incidentally, several reports are available in the literature regarding the synthesis of tetrazole compounds catalyzed by diverse type of nickel-based NPs. − Moreover, aldoxime derivatives have captured the attention of synthetic organic chemists during the past few years − because of their good reactivity and less toxic nature and the fact that they can be prepared very easily. Very recently, Patil, Babu, and Matsugi have reported, respectively, the homogeneous Cu­(OAc) 2 , InCl 3 , and DPPA catalyzed synthesis of 5-substituted 1 H -tetrazoles from aldoxime and sodium azide.…”

Tin powder‐promoted diastereoselective allylation of chiral acylhydrazones

“…Afterwards, more and more attention has been paid to tin powder‐promoted reactions. Especially, some reactions could be carried out in the presence of water or in pure water . This technique avoided the use of toxic stannanes while retaining their merits such as moisture stability, tolerance to functional groups and high selectivity .…”

Synthesis of homoallylic amines and acylhydrazides by tin powder‐promoted multicomponent one‐pot allylation reactions

“…Subsequently, allylations mediated by metallic tin were investigated in the presence of water or just using water as solvent, but most studies focused on allylation of aldehydes. [31,[51][52][53][54][55] Some other substrates such as nitroalkenes, [11] enol ethers [56] and aldoximes [57] were also allylated using allylic bromide and metallic tin in water to give homoallylic alcohols.…”