“…We have previously reported core–shell microspheres with a layered shell of inorganic nanoparticles prepared by a simple process involving modified suspension polymerization of monomer droplets containing inorganic particles, − microparticulation from phase-separated viscose containing inorganic particles, and hybridization of polymer microspheres and inorganic particles using supercritical carbon dioxide. , Various inorganic particles composed of silicon dioxide (silica), iron oxide, titanium oxide (titania), boron nitride, diamond, and carbon materials can be immobilized on the surface of polymer microspheres as the shell component. These core–shell microspheres with a layered shell of inorganic nanoparticles can be used as a precursor of hollow microspheres.…”