Coating is one of
the most important high-value-added application
cases in geopolymer materials. However, efflorescence can easily cause
discoloration and reduce the esthetic impression of the coating surface,
thus limiting its application; hence, inhibition of efflorescence
is one of the most important techniques in the application of geopolymer
coatings. Efflorescence is a spontaneous behavior in a Na-based geopolymer,
involving the migration of soluble alkalis. Alkalis are dissolved
by water and diffuse to the material surface through nocuous pores,
and then react with CO2 to produce white carbonate products.
To inhibit efflorescence in geopolymer coating, this article reports
a structure modification method using polydimethy siloxane (PS) and
mica. To explore the inhibition mechanism, the effects of PS and mica
on the pore structure, water absorption, alkali leaching, and efflorescence
product were investigated. The experimental results showed that a
harmful pore structure and instinctive water absorption of the geopolymer
strongly contributed to efflorescence. PS and mica could reduce the
pore size distribution and porosity and are helpful to establish a
waterproof structure, leading to water absorption and the alkali leaching
rate being significantly suppressed. Both high water glass and water
content play a critical role in the increase of efflorescence, but
even under a high content of water glass and water used in geopolymer
coating, this method shows an 80–90% efflorescence reduction,
which is much higher than that of other studies. In practical engineering,
when the geopolymer coating is applied after modification, even if
it is exposed to the field environment for a long time, there is no
efflorescence deposit on the coating surface. It is feasible to limit
water ingression in a geopolymer, which effectively blocks the efflorescence
reaction process. This method is simple and practical and can be applied
in practical engineering applications of geopolymer coatings conveniently.