“…Apart from the interest these systems have in themselves, they could also serve as a starting point to gain more understanding about the inclusion of chemical complexity effects in the electronic structure of periodic lattices, as well as of quasi-periodic, fractal and amorphous atomic or molecular sequences. Various quantum chain models, which are studied in the context of low-dimensional systems, have been treated with the transfer matrix method [28][29][30][31][32]. Here, we use the transfer matrix method [33,34] to solve the TB system of equations and determine expressions for its eigenvalues, for both cyclic and fixed boundary conditions, by combining the spectral duality relations [35,36] with the connection of the elements of the powers of a 2×2 unimodular matrix to the Chebyshev polynomials of the second kind [37,38].…”