“…1 Presently, Pb 1-x Sn x Se detectors are Schottky-induced p-n junctions; therefore achieving an in situ-grown p-n junction is a significant feat, as these devices have the potential to compete with presently available technology. 2 As a consequence, we expect a resurgence of these materials. Therefore, there is an increased need for an in-depth theoretical understanding of these material systems and devices particularly in regards to the relationship between material defects and device performance.…”