“…To this end, metal chalcogenides are exceptionally promising, because of their readily interchangeable binary and ternary compositions, their tendency to form well-defined 0D–3D dimensionalities at different composition thresholds, as well as their proven applications in electronics, − energy conversion, ,− and energy storage. ,, While much attention has been afforded to understand composition-dependent properties in transition-metal dichalcogenides (MX 2 ; M = transition metal; X = S, Se, Te) in particular, ,,,,, far fewer experimental investigations have been dedicated to understanding ternary chalcogenides such as the interesting one-dimensional (1D) M 2 Mo 6 X 6 (M= alkali metal; X = S, Se, Te) system, also known as pseudo-Chevrel–Phases (PCPs). − Besides the interesting properties associated with 1D systems due to electron confinement, − PCPs have been identified as alternative materials for nanodevices, because of their predicted high elasticity, stiffness, thermal stability, and conductivity. , Furthermore, properties that lend themselves to composites, , sensors, and photovoltaic devices have also been explored for this family of materials.…”