A graph G is uniquely k-colorable if the chromatic number of G is k and G has only one k-coloring up to permutation of the colors. For a plane graph G, two faces f1 and f2 of G are adjacent (i, j)faces if d(f1) = i, d(f2) = j and f1 and f2 have a common edge, where d(f ) is the degree of a face f . In this paper, we prove that every uniquely 3-colorable plane graph has adjacent (3, k)-faces, where k ≤ 5. The bound 5 for k is best possible. Furthermore, we prove that there exist a class of uniquely 3-colorable plane graphs having neither adjacent (3, i)-faces nor adjacent (3, j)-faces, where i, j ∈ {3, 4, 5} and i = j. One of our constructions implies that