2005
DOI: 10.1115/1.1845474
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On the Violence of High Explosive Reactions

Abstract: High explosive reactions can be caused by three general energy deposition processes: impact ignition by frictional and/or shear heating; bulk thermal heating; and shock compression. The violence of the subsequent reaction varies from benign slow combustion to catastrophic detonation of the entire charge. The degree of violence depends on many variables, including the rate of energy delivery, the physical and chemical properties of the explosive, and the strength of the confinement surrounding the explosive cha… Show more

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Cited by 25 publications
(11 citation statements)
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“…The refinement is seen both in additional observables and in the ability of models to demonstrate the phenomena observed as well as in the more precise nature of the questions being asked on subsequent experiments and models. Initial experiments on PBX 9501 yielded time to explosion as a function of boundary temperature with the ability to vary temperature, confinement, and void volume [27,28]. These experiments used spherical charges and uniform boundary temperature, making them essentially one-dimensional, thus the name one-dimensional time to explosion (ODTX).…”
Section: Small-scale Instrumented Thermal Ignition Experimentsmentioning
confidence: 99%
“…The refinement is seen both in additional observables and in the ability of models to demonstrate the phenomena observed as well as in the more precise nature of the questions being asked on subsequent experiments and models. Initial experiments on PBX 9501 yielded time to explosion as a function of boundary temperature with the ability to vary temperature, confinement, and void volume [27,28]. These experiments used spherical charges and uniform boundary temperature, making them essentially one-dimensional, thus the name one-dimensional time to explosion (ODTX).…”
Section: Small-scale Instrumented Thermal Ignition Experimentsmentioning
confidence: 99%
“…The problem of thermal decomposition during scenarios such as cook-off are routinely modeled using multi-step kinetics models where intermediate products are tracked and the rates are dependent on temperature. It is a goal to eventually model the impact and shock-induced reactions using the same modeling approach [36]. This option will be explored here using a model proposed in [40].…”
Section: Temperature Based Kineticsmentioning
confidence: 99%
“…During a slow heating process (slow cook-off), heat is conducted further into the explosive forming a uniform temperature distribution in the energetic material. In a slow cook-off, the point of ignition usually occurs near the center of the device and the explosion is observed to be very violent and may lead to detonation [29,2,32]. It is generally accepted that a slow cook-off leads to a more violent explosion than fast cook-off.…”
Section: Introductionmentioning
confidence: 99%
“…The violence of a thermal explosion is dependent upon numerous variables and conditions including the mechanical and thermal properties of the energetic material, the deflagration behavior, heating rate, and the degree of confinement [29,18]. These variables factor into the reaction rate which occurs after ignition of the energetic material.…”
Section: Introductionmentioning
confidence: 99%