On the thermodynamics of aggregation toward phosphorescent metallomesogens: From electronic tuning to supramolecular design
Matias E. Gutierrez Suburu,
Meik Blanke,
Leon Geerkens
et al.
Abstract:Two series with three Pt(II) complexes each (PtLPh‐n, PtLFpy‐n) bearing asymmetric tetradentate ligands as dianionic luminophores with variable alkyl chain lengths were synthesized. Hence, each ligand series is distinguished by one of its cyclometallating rings (phenyl vs. 2,6‐difluoropyrid‐3‐yl). Steady‐state and time‐resolved photoluminescence spectroscopic studies in diluted solutions at room temperature and in glassy matrices at 77 K show that the emissive state is mainly centered on the invariantly electr… Show more
“…This will broaden their applications in biomedical diagnosis and therapy, optoelectronic devices, multi-stimuli responsive systems, and sensing and detection. 109,110…”
“…This will broaden their applications in biomedical diagnosis and therapy, optoelectronic devices, multi-stimuli responsive systems, and sensing and detection. 109,110…”
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