On the ternary systems comprising water, a butanol isomer, and acetic or a chloroacetic acid

Legge, JW; Morieson, A. S.

doi:10.1071/ch9640707

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1984

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Cited by 2 publications

(3 citation statements)

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“…The alcohol and water were pipetted with analytical accuracy into the flask and titrated from a microburet with the acid until the mixture became homogeneous. The results of measurements in a water bath at 25 ± 0.1 °C were not different (within the experimental error) from those performed at room temperature (without thermostating), in accordance with earlier data (2,3).…”

Section: Methodssupporting

confidence: 92%

Composition of the ternary systems comprising water, n-butyl or isobutyl alcohol, and one of the four mineral acids HClO4, HNO3, HCl, or H2SO4

Molnár-Perl¹,

Kisfaludi²,

Pintér-Szakács³

1984

J. Chem. Eng. Data

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Unitarian entropy of dimerization (entropy corrected for the effect of the disappearance of a solute mole on dimerization) (15). This result is in good agreement with our previous results on acridine orange N-alkyl derivatives (6, 7) and is in favor of our suggestion, also proposed by other authors (16-20), on the dominant contribution of hydrophobic interactions to the association of these dyes in aqueous solution.

show abstract

Section: Methodssupporting

confidence: 92%

Composition of the ternary systems comprising water, n-butyl or isobutyl alcohol, and one of the four mineral acids HClO4, HNO3, HCl, or H2SO4

Molnár-Perl¹,

Kisfaludi²,

Pintér-Szakács³

1984

J. Chem. Eng. Data

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show abstract

“…The two phases in which the solutes were distributed were freshly prepared and used immediately so that esterification would be minimal (cf. Legge and Morieson 1964).…”

Section: Methodsmentioning

confidence: 99%

“…In view of the uncertainty as to the species present in the two phases (Legge and Morieson 1964) and of difficulties in the interpretation of the influence of nonionic and amphipathic substances on the structure of aqueous solutions [cf. Everett (and others) 1957] it would seem unprofitable to theorize on these empirical results.…”

Section: Dscussionmentioning

confidence: 99%