On the Tautomeric Structure of 5‐hydroxy‐ and 5‐mercapto‐1<i>H</i>‐1,2,3‐triazoles: <sup>−13</sup>C NMR analysis

L'abbé, G.; Delbeke, Pieter; Essche, Gonda van; Luyten, Ingrid; Vercauteren, Karin; Toppet, Suzanne

doi:10.1002/bscb.19900991119

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1993

2014

Publication Types

Select...

Article4

Book1

Relationship

Self Cite0

Independent5

Authors

Journals

Cited by 9 publications

References 24 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Study of The Diazoimine/Triazole Equilibria for Substituted Oxazoles and Oxadiazoles

L'abbé

Luyten

Vercauteren

et al. 1993

Bulletin des Soc Chimique

View full text Add to dashboard Cite

The diazoimine/triazole equilibria of diazo substituted azoles are not well documented in the literature. Data have been reported for thiazoles,1.* thiadiazoles, 1 thiatriazoles3 and tetrazoles.4 but no information is available for oxazoles and oxadiazoles. In this investigation we wanted to fill this gap by considering some diazo derivatives of the title compounds.The diazoacyl substituted azoles 1 (281, mp 85°C from CHC13/Et20), 2 (65%, mp 58°C from CHCI,/Et20), 3 (36%, mp 71°C from EtOH) and 4 (48%, mp 142°C from CHCI,/Et20) were prepared I3C NMR spectrum (DMSO-d6). The triazole form 8 was not observed. Ph J 8 CONHPh L 7

show abstract

Study of The Diazoimine/Triazole Equilibria for Substituted Oxazoles and Oxadiazoles

L'abbé

Luyten

Vercauteren

et al. 1993

Bulletin des Soc Chimique

View full text Add to dashboard Cite

show abstract

Réactions des Méthylazide et Phénylazide Avec Quelques Alcynes et Oléfines α‐Nitrées. Synthèse Régiospécifique des 1,2,3 Triazoles

Piet¹,

Hétet²,

Cailleux³

et al. 1996

Bulletin des Soc Chimique

View full text Add to dashboard Cite

The reactions of alkynes and a-nitro-olefines with methylazide and phenylazide was studied. In contrast to known reactions with alkynes which are non-regioselective, methylazide and phenylazide react regiospecifically with a-nitro-olefines and give only one type of triazole after elimination of HN02. These reactions are very useful synthetic approaches to 1,2,3 triazoles.Les 1,2,3 triazoles ont fait I'objet de nombreux

show abstract

NEW DATA ON THE TAUTOMERIC STRUCTURE OF 5‐MERCAPTO‐1H‐1,2,3‐ TRIAZOLES : ¹³C NMR AND X‐RAY STUDIES

Бакулев¹,

Morzherin²,

Atovmian³

et al. 1993

Bulletin des Soc Chimique

View full text Add to dashboard Cite

On the Tautomeric Structure of 5‐hydroxy‐ and 5‐mercapto‐1H‐1,2,3‐triazoles: ⁻¹³C NMR analysis

Cited by 9 publications

References 24 publications

Study of The Diazoimine/Triazole Equilibria for Substituted Oxazoles and Oxadiazoles

Study of The Diazoimine/Triazole Equilibria for Substituted Oxazoles and Oxadiazoles

Réactions des Méthylazide et Phénylazide Avec Quelques Alcynes et Oléfines α‐Nitrées. Synthèse Régiospécifique des 1,2,3 Triazoles

NEW DATA ON THE TAUTOMERIC STRUCTURE OF 5‐MERCAPTO‐1H‐1,2,3‐ TRIAZOLES : ¹³C NMR AND X‐RAY STUDIES

Contact Info

Product

Resources

About

On the Tautomeric Structure of 5‐hydroxy‐ and 5‐mercapto‐1H‐1,2,3‐triazoles: −13C NMR analysis

Cited by 9 publications

References 24 publications

Study of The Diazoimine/Triazole Equilibria for Substituted Oxazoles and Oxadiazoles

Study of The Diazoimine/Triazole Equilibria for Substituted Oxazoles and Oxadiazoles

Réactions des Méthylazide et Phénylazide Avec Quelques Alcynes et Oléfines α‐Nitrées. Synthèse Régiospécifique des 1,2,3 Triazoles

NEW DATA ON THE TAUTOMERIC STRUCTURE OF 5‐MERCAPTO‐1H‐1,2,3‐ TRIAZOLES : 13C NMR AND X‐RAY STUDIES

Contact Info

Product

Resources

About

On the Tautomeric Structure of 5‐hydroxy‐ and 5‐mercapto‐1H‐1,2,3‐triazoles: ⁻¹³C NMR analysis

NEW DATA ON THE TAUTOMERIC STRUCTURE OF 5‐MERCAPTO‐1H‐1,2,3‐ TRIAZOLES : ¹³C NMR AND X‐RAY STUDIES