On the Structure of Naphthalene Nucleus

Nakata, Nobuo

doi:10.1246/bcsj.10.318

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Dielectric Measurements2

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1966

2013

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“…Several other examples of peri interactions may be found among disubstituted naphthalenes. The observed dipole moment of 1,8-dichloronaphthalene is 2.88 D. (437). These are considerably lower than the calculated moments, assuming that the molecules are planar and that the dipole vectors act along the pert-bond axes (/icaicd for l,8-Ci0H6Cl2, 3.18 D.; for 1,8-Cio-H6(N02)2, ~8.0 D.).…”

Section: Dielectric Measurementsmentioning

confidence: 67%

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peri Interaction in Naphthalene Derivatives

1966

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Section: Dielectric Measurementsmentioning

confidence: 67%

“…Such a deflection has also been inferred from X-ray studies on 1,8-dinitronaphthalene (9). Nakata (437) has suggested an angle of 50°between -02 bonds.…”

Section: Dielectric Measurementsmentioning

confidence: 76%