“…Konnov's kinetic model 20 with the kinetic information obtained in this work for the reactions OH + HO2 → H2O + O2( 3 Σ g − ) and OH + HO2 → H2O + O2( 1 ∆g).…”
Section: Numerical Simulations Of the H2o2 Decompositionmentioning
confidence: 54%
“…Thus, the H2O2 decomposition at 1182 K and 1.672 atm is not significantly affected when the new rate constants for OH + HO2 → H2O + O2( 1 ∆g) are included in the kinetic model developed by Konnov. 20 We performed the same simulations at 1000 K, 1500 K and 1800 K and observed no differences in the H2O2 decomposition using Konnov…”
Section: Role Of the O2( 1 ∆G) In H2o2 Decomposition And In Cmentioning
confidence: 90%
“…Using these rate constants we updated the kinetic model recently developed by Konnov,20 which includes the rate constants from González et al 2 (singlet channel) and Hong et al 15 (triplet channel), to simulate the shock waves experiment by Hong et al 15 for H2O2 decomposition using CHEMKIN-PRO. The model was also used to estimate flame speeds and ignition delay times of different H2-oxidizer mixtures.…”