The Bell and Leggett-Garg tests offer operational ways to demonstrate that non-classical behavior manifests itself in quantum systems, and experimentalists have implemented these protocols to show that classical worldviews such as local realism and macrorealism are false, respectively. Previous theoretical research has exposed important connections between more general Bell inequalities and polyhedral combinatorics. We show here that general Leggett-Garg inequalities are closely related to the cut polytope of the complete graph, a geometric object well-studied in combinatorics. Building on that connection, we offer a family of Leggett-Garg inequalities that are not trivial combinations of the most basic Leggett-Garg inequalities. We then show that violations of macrorealism can occur in surprising ways, by giving an example of a quantum system that violates the new "pentagon" Leggett-Garg inequality but does not violate any of the basic "triangle" Leggett-Garg inequalities. The conventional setting for a Bell inequality involves two spacelike separated parties, say Alice and Bob, each of whom possess a quantum system A and B, respectively. Alice measures one of two dichotomic (±1-valued) observables A 1 or A 2 at her end, and Bob measures one of two dichotomic observables B 1 or B 2 at his end. The Clauser-Horne-Shimony-Holt (CHSH) Bell inequality [7] bounds the following sum of two-point correlation functions in any local realistic theory:A bipartite quantum system in an entangled state can violate the above inequality, demonstrating that the local realistic picture of the universe is false.Bell inequalities beyond the above conventional twoparty, two-observable setting admit a rich mathematical structure. Peres showed that they correspond to the facets of a convex polytope, which he called the Bell polytope [8]. It is an example of a correlation polytope, which have been much studied, see for example Ref.[9] and the encyclopedic Ref. [10]. Avis et al. described a relationship between the Bell polytope and a projecion of the cut polytope [11,12], a polytope which is isomorphic to the correlation polytope, and studied in depth in Ref.[10]. They were then able to offer 44,368,793 inequivalent tight Bell inequalities other than those of the CHSH form for the bipartite setting where each party measures ten dichotomic observables [11].The conventional setting for an LGI involves a single party, say Quinn, who possesses a single quantum system. Quinn measures three dichotomic observables Q 1 , Q 2 , and Q 3 as his system evolves in time [18]. The LGI bounds a sum of two-time correlation functions in any macrorealistic theory:Quinn can obtain the correlators Q 1 Q 2 , Q 2 Q 3 , and Q 1 Q 3 with many repetitions of one experiment where he measures all three observables, or he can obtain them with many repetitions of three different experiments where each experiment measures only the observables in a single correlator Q i Q j . Note, for example, that if the system behaves according to the postulates of macrorealism, it...