The 4p-subshell spectrum of Mo+
has been recorded, for the first time, in the wavelength range 500–200
Å. The spectrum is dominated by a 4p → 4d
‘giant resonance’ on which extensive discrete structure is superposed.
With only one exception the discrete lines can be ordered into six
Rydberg series, 4p64d56S
5/2 → 4p5(4d56S)(7P)ns,nd (J = 3/2, 5/2, 7/2),
converging on three limits, the Mo III levels 4p5(4d56S)7P
4,3,2.
The observed spectrum is analysed by comparison with both Hartree plus
exchange with relativistic corrections and relativistic time-dependent local density
approximation calculations. The evolution of the discrete structure line shapes
interacting with the giant resonance is found to be in qualitative agreement with
the theory of Connerade and Lane (1987 J. Phys. B: At. Mol. Phys. 20 L181–6).