Abstract:The free radical precipitation copolymerization of the polar monomer glycidyl methacrylate (GMA) and the nonpolar monomer 1‐octene (Oct) in supercritical carbon dioxide (sc‐CO2) is reported under different conditions of pressure and temperature. According to 1H NMR studies, in the obtained statistical copolymers (GMA‐stat‐Oct) the molar fraction of the olefin (FOct) increases when the pressure and temperature of the reaction increased from the reference values T = 125 °C and P = 34 bar. In particular, when the… Show more
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