Fuel and synthesis gases generated by thermochemical gasification of renewable biomass resources and organic waste fractions are considered to be promising for recent and future energy demands. However, the presence of tar species in the gas mixture is an economic obstacle in the commercialization of this technology. The influence of non-thermal plasma on gas phase naphthalene (C10H8), which served as tar model compound, in the presence of solids was examined. The naphthalene was evaporated into a N2/H2/CO/CO2 gas atmosphere and led through a packed-bed, atmospheric plasma reactor operated at a temperature of 350 • C. The influence of two bed materials -glass beads and glass beads mixed with char particles -was studied. The char particles originated from real gasification processes with woody biomass as feedstock. With both reactor fillings, the content of naphthalene in the gas phase was reduced. The characteristic energy β of the naphthalene removal was found to be β no char = 952 ± 77 Jl −1 and β with char = 232 ± 10 Jl −1 , respectively. Consequently, the addition of char material leads to a naphthalene removal efficiency increased by a factor of about four. Furthermore the formation of ammonia (NH3), a by-product of the plasma reactions, was suppressed in the presence of char.