A quantum-mechanical calculation of the probability of an elementary exoelectron emission (EEE) act from a NaCl crystal is made. The mechanism previously suggested by the authors is used, according to which the emission takes place a t the expense of the energy released a t exoenergetic reactions between defects. The calculations are made for the particular case of annihilation of the F-centre with a negative halide atom. There is good agreement between theory and experimental results. IIonyYeHo xopomee cosnanemie TeOpllH C 3KCIlepLIMeHTaJlbHbIMH pe3yJIbTaTaMH.