On the photopolymerization of mevalonic lactone methacrylate: exposing the potential of an overlooked monomer

Esen, Cansu; Antonietti, Markus; Kumru, Baris

doi:10.1039/d1py01497h

Cited by 2 publications

(2 citation statements)

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“…[18,19] So-formed radicals are then employed for radical polymerization of vinyl-containing monomers. [20] Nevertheless, the influence of photoredox chemistry is expanding in polymer science to access more advanced mechanisms. [21,22] The power of solar irradiation was demonstrated not only for the synthesis of polymers but also for depolymerization.…”

Section: Introductionmentioning

confidence: 99%

Light‐Enabled Access to Oxidative Polymerization: A Short Perspective on Bioinspired Oxidative Photopolymerization

Kumru

2022

Solar RRL

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Figure 1. a) Polymerization mechanism of pyrrole initiated by solar irradiation using iodonium salt complexes and photosensitizer. Adapted with permission. [41] Copyright 2015, Elsevier. b) Photooxidative polymerization of EDOT trimer using perovskite nanocrystals. Adapted with permission. [45] Copyright 2017, American Chemical Society. c) Depiction of shift in Fermi level in semiconductor heterojunction by different wavelength which enables oxidation of monomers to initiate polymerization. Adapted with permission. [46] Copyright 2020, American Chemical Society. d) Oxidative photopolymerization of EDOT in printed composite sample using ruthenium complexes. Adapted under the terms of the CC BY 4.0 license. [49]

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Section: Introductionmentioning

confidence: 99%

Light‐Enabled Access to Oxidative Polymerization: A Short Perspective on Bioinspired Oxidative Photopolymerization

Kumru

2022

Solar RRL

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“…[12,13] In research, radical polymerization remains the technological workhorse mainly due to its simplicity and efficiency toward vinyl monomers. [14,15] Soluble polymers in this case possess high polydispersity, hence for polymer molecular architecting controlled molecular weights and polydispersities are required. [16] Controlled radical polymerization broke new grounds and brought synthetic chemistry closer to natural systems.…”

Section: Introductionmentioning

confidence: 99%

Emerging Concepts in Iodine Transfer Polymerization

Kumru

Antonietti

2022

Macro Chemistry & Physics

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Controlled radical polymerization corresponds to variety of synthetic strategies that aim the generation of precise macromolecular architectures. Iodine transfer polymerization (ITP) is one of the oldest methods to conduct controlled radical polymerization; however, it seems to have lost visibility compared to other popular techniques. It relies on utilization of iodine species in reversible deactivation kinetics, and it has some significant advantages compared to other methods. Its simplicity, minimized toxicity, metal-free nature, no coloring on final product, and ease of purification provide widespread applicability, even in industry. In this perspective, the basics of ITP are re-introduced, and emerging technologies (heterophase polymerization, photoinitiation, and sustainability) in ITP are discussed.

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On the photopolymerization of mevalonic lactone methacrylate: exposing the potential of an overlooked monomer

Abstract: Functional polymers remain at the core of polymer science in the second century of macromolecular materials. Lactones are known as monomers for ring opening polymerizations; however polymers containing lactone rings...

Cited by 2 publications

References 31 publications

Light‐Enabled Access to Oxidative Polymerization: A Short Perspective on Bioinspired Oxidative Photopolymerization

Light‐Enabled Access to Oxidative Polymerization: A Short Perspective on Bioinspired Oxidative Photopolymerization

Emerging Concepts in Iodine Transfer Polymerization

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