1975
DOI: 10.1002/pssb.2220700148
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On the Optical Spectrum of CdCl2:Mn Single Crystals

Abstract: BY 2+Crystal field spectra of the Mn ion in pure MnCl o r highly concentrated (over

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Cited by 11 publications
(1 citation statement)
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“…Nevertheless in CdF 2 :Mn 2+ and CaF 2 :Mn 2+ [24], where it is well known that the 3d ion-ligand distance is large, Dq values similar to the one found in our glass have been found. In the same way, the B and C parameters for the most concentrated samples in chlorine and bromine ions are similar to those obtained in chloride and bromide crystals but the Dq values are smaller than in crystals [19,[26][27][28][29]. Some authors indicate that this effect is due to the fact that the 3d ion is placed in the Ba 2+ ion position, which has a large ionic radius and a very strong modifier character in ZBLAN glasses [12].…”
Section: Crystal Field Calculationssupporting
confidence: 69%
“…Nevertheless in CdF 2 :Mn 2+ and CaF 2 :Mn 2+ [24], where it is well known that the 3d ion-ligand distance is large, Dq values similar to the one found in our glass have been found. In the same way, the B and C parameters for the most concentrated samples in chlorine and bromine ions are similar to those obtained in chloride and bromide crystals but the Dq values are smaller than in crystals [19,[26][27][28][29]. Some authors indicate that this effect is due to the fact that the 3d ion is placed in the Ba 2+ ion position, which has a large ionic radius and a very strong modifier character in ZBLAN glasses [12].…”
Section: Crystal Field Calculationssupporting
confidence: 69%