On the modelling of semi-insulating GaAs including surface tension and bulk stresses

Abstract

The necessary heat treatment of single-crystal semi-insulating gallium arsenide (GaAs), which is deployed in micro-and optoelectronic devices, generates undesirable liquid precipitates in the solid phase. The appearance of precipitates is influenced by surface tension at the liquid-solid interface and deviatoric stresses in the solid.The central quantity for the description of the various aspects of phase transitions is the chemical potential, which can be additively decomposed into a chemical and a mechanical part. In particular, the calculation of the mechanical part of the chemical potential is of crucial importance. We determine the chemical potential in the framework of the St. Venant-Kirchhoff law, which gives an appropriate stress-strain relation for many solids in the small-strain regime. We establish criteria that allow the correct replacement of the St. Venant-Kirchhoff law by the simpler Hooke law.The main objectives of this study are the following: (i) we develop a thermomechanical model that describes diffusion and interface motions, which are both strongly influenced by surface tension effects and deviatoric stresses, (ii) we give an overview and outlook on problems that can be posed and solved within the framework of the model, and (iii) we calculate non-standard phase diagrams for GaAs above 1059 K, i.e. those that take into account surface tension and deviatoric stresses, and we compare the results with classical phase diagrams without these phenomena.

Boron‐ and stoichiometry‐related defect engineering during B2O3‐free GaAs crystal growth

“…This is due to the fact that the chemical and physical methods, available to determine the deviation from stoichiometry in GaAs, are not precisely enough. Latest thermodynamic calculations confirm experimental results of the homogeneity range, which seems to be completely located on the As-rich side [15]. To our best knowledge not any contrary experimental evidences are known.…”

The behavior of a many-particle electrode in a lithium-ion battery

“…The free energy density satisfies the Gibbs equation and the Gibbs-Duhem equations; see [22,21]. These read…”

TEM investigation of precipitates in VCz GaAs crystals

“…First, the exact shape of the homogeneity range of the phase diagram is not yet known. According to the recent thermodynamic approach [16], only As-rich GaAs exists independent of the Ga-richness of the melt composition. The Ga-rich correlated solidus course seems to be nearly perpendicular and very close to the stoichiometric line, but always deviates to the As-rich side.…”