A digraph is 3-dicritical if it cannot be vertex-partitioned into two sets inducing acyclic digraphs, but each of its proper subdigraphs can. We give a human-readable proof that the number of 3-dicritical semi-complete digraphs is finite. Further, we give a computer-assisted proof of a full characterization of 3-dicritical semi-complete digraphs. There are eight such digraphs, two of which are tournaments. We finally give a general upper bound on the maximum number of arcs in a 3-dicritical digraph.