Understanding and mastering initial status in eutectic area (γ′–γ) of Ni3Al‐based alloy under solution treatment conditions are beneficial to its aging treatment and applications. In this work, optimal solution treatment process parameters of JG4246A Ni3Al‐based alloy are investigated based on microstructure observation, chemical composition analysis, and micro‐hardness test. Results show that the alloy with solution temperature of 1270 °C for 6 h possess smoother eutectic area (γ′–γ) boundaries, more stable carbides, and relatively higher micro‐hardness. More importantly, to clarify the evolution behavior of Ni3Al (γ′) phase in eutectic area (γ′–γ) under solution treatment conditions, short‐time (3 h) and long‐time (18 h) solution treatments at 1270 °C are applied and the evolution behavior is analyzed by TEM. Results show that plenty of spherical Ni3Al (γ′) phase appears in eutectic area (γ′–γ), with its dimensions changing little with solution time increasing. Vacancies, lattice distortion, and thermo‐stress mainly contribut to the precipitation and growth of spherical Ni3Al (γ′) phase.