In this paper, we study the hyperbolicity constant of GG. In particular, we obtain upper and lower bounds for the hyperbolicity constant, and we compute its precise value for many graphs. Moreover, we obtain bounds and closed formulas for the general topological indices A(GG) = ∑ uv∈E(GG) a(d u , d v ) and B(GG) = ∑ u∈V(GG) b(d u ) (where d u denotes the degree of the vertex u, a is a symmetric function with real values, and b is a function with real values), and the generalized Wiener index W 𝜆 (GG), of complementary prisms networks. Finally, we performed a numerical study of the generalized Wiener index on random graphs.