We observed thirteen Planck cold clumps with the James Clerk Maxwell Telescope/SCUBA-2 and with the Nobeyama 45 m radio telescope. The N 2 H + distribution obtained with the Nobeyama telescope is quite similar to SCUBA-2 dust distribution. The 82 GHz HC 3 N, 82 GHz CCS, and 94 GHz CCS emission are often distributed differently with respect to the N 2 H + emission. The CCS emission, which is known to be abundant in starless molecular cloud cores, is often very clumpy in the observed targets. We made deep single-pointing observations in DNC, HN 13 C, N 2 D + , cyclic-C 3 H 2 toward nine clumps. The detection rate of N 2 D + is 50%. Furthermore, we observed the NH 3 emission toward 15 Planck cold clumps to estimate the kinetic temperature, and confirmed that most of targets are cold ( 20 K). In two of the starless clumps observe, the CCS emission is distributed as it surrounds the N 2 H + core (chemically evolved gas), which resembles the case of L1544, a prestellar core showing