On the Crystal Structure of the Neodymium Iminodiacetate Compound Nd2(C4H5O4N)3.2HCl.7H2O.

Albertsson, J.; Oskarsson, Åke; Glehn, Marianne von; Tolboe, O.; Paasiv́irta, Jaakko

doi:10.3891/acta.chem.scand.22-1700

Cited by 25 publications

(8 citation statements)

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“…In these structures the iminodiacetic acid residue acts as a monodentate or a tridentate ligand coordinated to lanthanoid(III) ions (Albertsson & Oskarsson, 1968;Oskarsson, 1971) or as a donor of hydrogen bonds to halide ions (Oskarsson, 1973). The organic molecule shows a large conformational variation in these compounds.…”

Section: Crystal Datamentioning

confidence: 99%

The crystal and molecular structure of a monoclinic phase of iminodiacetic acid

Boman¹,

Herbertsson²,

Oskarsson³

1974

Acta Crystallogr Sect B

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Section: Crystal Datamentioning

confidence: 99%

The crystal and molecular structure of a monoclinic phase of iminodiacetic acid

Boman¹,

Herbertsson²,

Oskarsson³

1974

Acta Crystallogr Sect B

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“…In a research program at this Institute dealing with rare earth carboxylates the crystal and molecular structures of the neodymium iminodiacetate compounds Nd2(C4HsNO4)3 2HC1.7H20 (Albertsson & Oskarsson, 1968) and Nd(C4HsNO4)C1.3H20 (Oskarsson, 1971) have been determined. In order to investigate how the geometry of the organic molecule is affected by different crystallographic surroundings, a systematic study of the compounds CaHTNO4.HX, where X = F, C1, Br or I, has been commenced.…”

Section: Introductionmentioning

confidence: 99%

The crystal and molecular structures of iminodiacetic acid hydrochloride, C4H7NO4.HCl and iminodiacetic acid hydrobromide, C4H7NO4.HBr

Oskarsson¹

1973

Acta Crystallogr B Struct Crystallogr Cryst Chem

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The crystal and molecular structures of iminodiacetic acid hydrochloride, C4H7NO4. HC1, and iminodiacetic acid hydrobromide, C4H7NO4.HBr, have been determined by a symbolic addition method with three-dimensional single crystal X-ray data obtained on a diffractometer. The compounds are isostructural, crystallizing in the orthorhombic space group Pmmn with Z= 2. The unit-cell dimensions are a= 12.4101, b= 5.7349, c=5.1280 A~ and a= 12.8150, b= 5.8705, e=5.0870/~ for the chloride and bromide respectively. Positively charged iminodiacetic acid ions are connected by hydrogen bonds via the halide ions and zigzag layers are formed. These layers are stacked in the c direction and the forces between the layers are of van der Waals type.

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“…Especially, lanthanide contraction usually plays an important role in the topological structure of lanthanide coordination polymers [7][8][9][10][11][12][13][14][15][16][17][18]. On the other hand, iminodiacetic acid (H 2 IDA), featuring unique chelate carboxyl and amido, had been widely applied to synthesize high lanthanide-transition metal (3d-4f) heterometallic clusters and coordination polymers [19][20][21][22][23][24], whereas corresponding studies with respect to its lanthanide coordination polymers are relative rare [25,26]. N-(sulfoethyl) iminodiacetic acid, serving as one derivative of H 2 IDA, not only inherits intrinsic characteristics of H 2 IDA but also consists of a new sulfonate.…”

Section: Introductionmentioning

confidence: 99%