On the Concentration Fluctuation and Ordering Potential of LiPb in the Bhatia‐Young Approach

Abstract

An ordering potential out of the Thomas-Fermi type interaction between dissimilar species based on the concept of charge transfer and hence concentration dependent, is constructed to study the thermodynamic properties of the Li-Pb alloy in the Bhatia-Young formalism. It is seen to be fairly successful in predicting the experimental behaviour of concentration fluctuation and the excess stability in the system.