2009
DOI: 10.1016/j.fluid.2009.07.021
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On the computation of the fundamental derivative of gas dynamics using equations of state

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Cited by 37 publications
(31 citation statements)
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“…The experimental proof of nonclassical gasdynamic effects in flows of dense vapors has been the subject of several studies [2,3,1], most of all focused on a shock tube configuration for generating a rarefaction shock wave (RSW). These works show that nonclassical gasdynamic effects are generally very weak with respect to compression shock waves, and can occur only in a limited range of conditions.…”
Section: Introductionmentioning
confidence: 99%
“…The experimental proof of nonclassical gasdynamic effects in flows of dense vapors has been the subject of several studies [2,3,1], most of all focused on a shock tube configuration for generating a rarefaction shock wave (RSW). These works show that nonclassical gasdynamic effects are generally very weak with respect to compression shock waves, and can occur only in a limited range of conditions.…”
Section: Introductionmentioning
confidence: 99%
“…The resulting probabilities are not normalized but it is clear that P( N 1 , V , E ) = 1, irrespective of how many terms are included in Equation (7). It should be noted that, using an entropy expansion approach beyond Gaussian, it is problematic to assume that the mean values of N 1 , V, and E are also the most probable values.…”
Section: Ds/rmentioning
confidence: 99%
“…4 Equilibrium fluctuations can be related to a series of thermodynamic properties (derivatives), and play an integral role in a variety of fluctuationdissipation theorem based relationships, 5,6 and other fluid behaviors. 7,8 The majority of approaches involve an expansion of the entropy. The most common treatment of fluctuations is provided by Landau and Lifshitz, 9 while a more extensive discussion was recently provided by Mishin.…”
Section: Introductionmentioning
confidence: 99%
“…Real gas effects are particularly strong for highly complex molecules which display a non-monotonic variation of the sound speed with respect to pressure. Some fluids characterized by particularly high molecular complexity have been theoretically predicted [7][8][9][10] to display a region of negative values of the fundamental derivative of fluid dynamics C [11] in the vapor phase. This thermodynamic region is called the inversion zone [12] and the locus of thermodynamic states in the vapor phase such that C < 0 is referred to as the transition line.…”
Section: Introductionmentioning
confidence: 99%