On the comments of R. V. Figini to the article “mechanism of anionic polymerization of styrene by living polystyrilsodium”

Korotkov, A.; Podolsky, A. F.

doi:10.1002/pol.1969.110070201

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1983

1991

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“…There is a sufficient dissimetry in the cyclohexane solutions (2 = 1&/1135 TT. 3) showing the existence of large particles while in the base lubricating oil 2 = 1.1 and indicates that the particles are more compact.…”

Section: Resultsmentioning

confidence: 96%

Styrene–isoprene block copolymers. I. Synthesis and solution properties

Velichkova

Toncheva

Getova³

et al. 1991

J. Polym. Sci. A Polym. Chem.

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Copolymers with a different degree of distribution of styrene and isoprene blocks are prepared by anionic polymerization. The products are characterized by means of 1H‐NMR spectroscopy, GPC, viscometry, and light scattering. The results show that the copolymers are homogeneous in molecular weight and chain composition. In the investigated selective solvents, cyclohexane and base lubricating oil, and equilibrium exists between micelle aggregates and individual polymer coils. The influence of the copolymer structure on the micellization is more pronounced in cyclohexane.

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Section: Resultsmentioning

confidence: 96%