In this article, we give a classification of closed, smooth, spin, 1connected 7-manifolds whose integral cohomology ring is isomorphic to that of CP 2 ×S 3 . We also prove that if a closed, smooth, spin, 1-connected 7-manifold has integral cohomology ring isomorphic to that of CP 2 ×S 3 or S 2 ×S 5 , then it admits a Riemannian metric with positive Ricci curvature.