In this work we study a problem of finding minimum coloured paths in graphs that has applications in WDM optical networks when high bandwidths are required to send data between a pair of nodes in the graph. Let G = (V, E) be a (directed) graph with a set of nodes V and a set of edges E in which each edge has an associated positive weight w(i, j), and C = {1, 2, . . . , x} be a set of x colours, x ∈ N. The function c : E → 2 C maps each edge of the graph G to a subset of colours, where 2 C is the power set of C. Given a positive integer k > 1, a k-multicolour path is a path in G such that there exists a set of k colours K = {c 1 , . . . , c k } ⊆ C, with K ⊆ c(i, j) for each edge (i, j) in the path.The problem of finding one or more k-multicolour paths in a graph has applications in optical network and social network analysis. In the former case, the available wavelengths in the optical fibres are represented by colours in the edges and the objective is to connect two nodes through a path offering a minimum required bandwidth. For the latter case, the colours represent relations between elements and paths help identify structural properties in such networks.In this work we investigate the complexity of the multicolour path establishment problem. We show it is NP-hard and hard to approximate. Additionally, we develop Branch and Bound algorithms, ILPs, and heuristics for the problem. We then perform an experimental analysis of the developed algorithms to compare their performances.