On the Application of the Pseudophase Model to Excited State Processes: Quenching of Pyrene by the Iodide Ion in β‐Cyclodextrin and Micellar (SDS) Solutions
Abstract:The pseudophase model, a two‐state model, is based on the assumption of the existence of an equilibrium between these two states (free and bound), which is not perturbed in the case of a reactive event. This implies that the processes in which these two states participate must be slow, in relation to the exchange processes between these states. This condition does not hold in the case of very rapid photochemical quenching processes. However, for these processes the pseudophase model is formally applicable. In … Show more
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