The pinch-off of the leading vortex ring at a critical time scale, defined as the formation number (Gharib et al., 1998), has been identified as an important phenomenon for vortex ring formation in a starting jet. Previous researchers have also demonstrated the effect of non-impulsive velocity program on delaying the onset of pinch-off process and generating thicker vortex ring. Thus, experiments in present study focus on starting jets with different velocity programs and Reynolds numbers (Re = 2600, 4100, 5600) so as to determine the detailed characteristics of the pinch-off process. Digital Particle Image Velocimetry (DPIV) has been used to measure the velocity field, from which vorticity, circulation, impulse, kinetic energy and vortex ring trajectories can be derived. Based on the prediction on the dynamic fluxes fed into the leading vortex ring, an analytical model for the pinch-off process is subsequently developed. The properties of the leading vortex ring in a gravity-driven starting circular jet with converging nozzle are first analyzed based on the experimental results of Ai (2006), as a comparison to those generated by the piston-cylinder arrangement. It is proven that the properties of the pinched-off vortex ring in a gravity-driven jet are consistent with those for the piston-cylinder arrangement. The dimensionless circulation γ and energy α are found to be around 1.85 and 0.33 respectively. The result suggests that the leading vortex rings in the gravity-driven starting circular jet can also be approximated as the Norbury-Fraenkel family of vortex rings, which is of great importance in modelling the vi