Global efforts for environmental cleanliness through the control of gaseous emissions from vehicles are gaining momentum and attracting increasing attention. Calibration plays a crucial role in these efforts by ensuring the quantitative assessment of emissions for informed decisions on environmental treatments. This paper describes a method for the calibration of CO/CO 2 monitors used for periodic inspections of vehicles in cites. The calibration was performed in the selected ranges: 900 -12,000 µmol/mol for CO and 2000 -20,000 µmol/mol for CO 2 . The traceability of the measurement results to the SI units was ensured by using certified reference materials from CO/N 2 and CO 2 /N 2 primary gas mixtures. The method performance was evaluated by assessing its linearity, accuracy, precision, bias, and uncertainty of the calibration results. The calibration data exhibited a strong linear trend with R² values close to 1, indicating an excellent fit between the measured values and the calibration lines. Precision, expressed as relative standard deviation (%RSD), ranged from 0.48 to 4.56% for CO and from 0.97 to 3.53% for CO 2 , staying well below the 5% threshold for reporting results at a 95% confidence level. Accuracy measured as percent recovery, was consistently high (≥ 99.1%) for CO and ranged from 84.90% to 101.54% across the calibration range for CO 2 . In addition, the method exhibited minimal bias for both CO and CO 2 calibrations and thus provided a reliable and accurate approach for calibrating CO/CO 2 monitors used in vehicle inspections. Thus, it ensures the effectiveness of exhaust emission control for better environment.