On phosphorus chemical shift anisotropy in metal (IV) phosphates and phosphonates: A ³¹P NMR experimental study

Abstract

The phosphorus chemical shift anisotropies, 31 PΔcs, and asymmetry parameters η were measured by the 31 P{ 1 H} NMR experiments in static and lowfrequency spinning samples of the zirconium phosphates and phosphonates and also in the mixed Zr (IV)/Sn (IV) phosphate/phosphonate material. The data obtained have shown a 111 connectivity in the HPO 4 and PO 3 groups, which does not change at modification and intercalation of the materials. The 31 PΔcs values of the phosphonate groups (43-49 ppm) significantly surpass the values characterizing the HPO 4 groups (23-37 ppm). The 31 P Δcs values obtained for the metal (IV) phosphates were discussed in terms of P-O distances. The 31 P chemical shift anisotropy parameters can help at elucidation of local structures in phosphate and phosphonate materials.