Recent photometric and polarimetric observations of type Ia supernovae (SNe Ia) show unusually low total-to-selective extinction ratio (R V < 2) and wavelength of maximum polarization (λ max < 0.4 µm) for several SNe Ia, which indicates peculiar properties of interstellar (IS) dust in the SN hosted galaxies and/or the presence of circumstellar (CS) dust. In this paper, we use inversion technique to infer bestfit grain size distribution and alignment function of interstellar grains along the lines of sight toward four SNe Ia with anomalous extinction and polarization data (SNe 1986G, 2006X, 2008fp, and 2014J). We find that to reproduce low values of R V , a significant enhancement in the mass of small grains of radius a < 0.1 µm is required. For SN 2014J, a simultaneous fit to its observed extinction and polarization is unsuccessful if the entire data are attributed to IS dust (model 1), but a good fit is obtained when accounting for the contribution of CS dust (model 2). For SN 2008fp, our best-fit results for model 1 show that, to reproduce an extreme value of λ max ∼ 0.15 µm, small silicate grains must be aligned as efficiently as big grains. For this case, we suggest that strong radiation from the SN can induce efficient alignment of small grains in a nearby intervening molecular cloud via radiative torque mechanism. The resulting time dependence polarization from this RAT alignment model can be tested by observing at ultraviolet wavelengths.