Onsets of electron density enhancements in the upper nighttime mesosphere produced by electric field heating of electrons are examined using a photochemical model that accounts for 29 dynamic species via a set of 156 reactions. Physical mechanisms are identified which result in electron density enhancements that continuously increase for up to several seconds after electric field heating, establishing the conditions under which early VLF scattering is either “fast” (<20 ms) or slower(>20 ms, including “slow,” ≥500 ms). During heating, O− ions are produced by heterolysis, e− + O2 → e− + O− + O+, and dissociative attachment, e−+ O2 → O− + O. Following heating, a significant proportion of O− ions associatively detach with molecular oxygen, O− + O2 → O3 + e−, and atomic oxygen, O− + O → O2 + e−. If enough O− ions are produced during heating such that O− detachment exceeds electron loss (predominantly attachment, e− + O3 →
normalO2− + O, and/or electron‐ion recombination), electron densities will continue to increase after heating has ended. Consequently, the total risetime of electron density enhancements produced by electric field heating is controlled by the duration of the electric field heating and (in some cases) the effects of O− detachment following heating.