Let m ≥ −1 be an integer. We give a correspondence between integer solutions to the parametric family of cubic Thue equationswhere λ > 0 is a divisor of m 2 + 3m + 9 and isomorphism classes of the simplest cubic fields. By the correspondence and R. Okazaki's result, we determine the exactly 66 non-trivial solutions to the Thue equations for positive divisors λ of m 2 + 3m + 9. As a consequence, we obtain another proof of Okazaki's theorem which asserts that the simplest cubic fields are non-isomorphic to each other except for m