We establish a bialgebra structure on Rota-Baxter Lie algebras following the Manin triple approach to Lie bialgebras. Explicitly, Rota-Baxter Lie bialgebras are characterized by generalizing matched pairs of Lie algebras and Manin triples of Lie algebras to the context of Rota-Baxter Lie algebras. The coboundary case leads to the introduction of the admissible classical Yang-Baxter equation (CYBE) in Rota-Baxter Lie algebras, for which the antisymmetric solutions give rise to Rota-Baxter Lie bialgebras. The notions of O-operators on Rota-Baxter Lie algebras and Rota-Baxter pre-Lie algebras are introduced to produce antisymmetric solutions of the admissible CYBE. Furthermore, extending the well-known property that a Rota-Baxter Lie algebra of weight zero induces a pre-Lie algebra, the Rota-Baxter Lie bialgebra of weight zero induces a bialgebra structure of independent interest, namely the special L-dendriform bialgebra, which is equivalent to a Lie group with a left-invariant flat pseudo-metric in geometry. This induction is also characterized as the inductions between the corresponding Manin triples and matched pairs. Finally, antisymmetric solutions of the admissible CYBE in a Rota-Baxter Lie algebra of weight zero give special L-dendriform bialgebras and in particular, both Rota-Baxter algebras of weight zero and Rota-Baxter pre-Lie algebras of weight zero can be used to construct special L-dendriform bialgebras.