Omnidirectional Energy Harvesting Fleeces

Abstract

Underwater mechanical energy harvesters are of rising interest due to their potential for various applications, such as self-powered ocean energy harvesters, monitoring devices, and wave sensors. Pressure-responsive films and stretch-responsive fibers, which provide high electrical power in electrolytes and have simple structures that do not require packing systems, are promising as harvesters in the ocean environment. One drawback of underwater mechanical energy harvesters is that they are highly dependent on the direction of receiving external forces, which is unfavorable in environments where the direction of the supplied force is constantly changing. Here, we report spherical fleece, consisting of wool fibers and single-walled carbon nanotubes (SWCNTs), which exhibit repetitive electrical currents in all directions. No matter which direction the fleece is deformed, it changes the surface area available for ions to access SWCNTs electrochemically, causing a piezoionic phenomenon. The current per input mechanical stress of the fabricated SWCNT/wool energy harvester is up to 33.476 mA/MPa, which is the highest among underwater mechanical energy harvesters reported to date. In particular, it is suitable for low-frequency (<1 Hz) environments, making it ideal for utilizing natural forces such as wind and waves as harvesting sources. The operating mechanism in the nanoscale region of the proposed fleece harvester has been theoretically elucidated through all-atom molecular dynamics simulations.