2003
DOI: 10.1016/j.radphyschem.2003.06.001
|View full text |Cite
|
Sign up to set email alerts
|

Oligomer formation in the radiation-induced polymerization of styrene

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1
1
1

Citation Types

1
1
0

Year Published

2008
2008
2020
2020

Publication Types

Select...
5

Relationship

1
4

Authors

Journals

citations
Cited by 5 publications
(3 citation statements)
references
References 16 publications
1
1
0
Order By: Relevance
“…The main spectral feature observed is an absorption band with a maximum of approximately 315 nm to 320 nm. This observation generally agrees with results reported elsewhere (47, 48). The capture of the solvated electrons by styrene to produce styrene anion and cation radicals is extremely fast (49).…”
Section: Resultssupporting
confidence: 94%
“…The main spectral feature observed is an absorption band with a maximum of approximately 315 nm to 320 nm. This observation generally agrees with results reported elsewhere (47, 48). The capture of the solvated electrons by styrene to produce styrene anion and cation radicals is extremely fast (49).…”
Section: Resultssupporting
confidence: 94%
“…The generally accepted mechanism of this thermally initiated free‐radical polymerization comprising the formation of the main dimers and trimers can be described as shown in Scheme 1–5. Recently, the formation of oligomers has been of special interest in radiation‐induced styrene polymerization and gas‐phase thermal polymerization of styrene and in theoretical calculations of the mechanism of the self‐initiated thermal polymerization of styrene 6–8…”
Section: Introductionmentioning
confidence: 99%
“…IDT show minimum values for the samples exposed to maximum dose (10.5 MGy) of high intensity irradiation. This may be due to formation of more oligomers (molecular complex that consists of few monomers) [17] due to high intensity of irradiation. These oligomers exhibit early thermal decomposition.…”
Section: Tga Analysismentioning
confidence: 99%