Oils sorption on hydrophobic nanocellulose aerogel obtained from the wood furniture industry waste

Oliveira, Pablo Beluck de; Godinho, Marcelo; Zattera, Ademir J.

doi:10.1007/s10570-018-1781-8

Cited by 40 publications

(15 citation statements)

References 45 publications

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“…2e and Movie S2). Moreover, the water contact angle achieved by the PVDF/PI aerogel is much higher than other hydrophobic materials including PAN/carbon nanotube/Fe 3 O 4 aerogel [6], nanocellulose aerogel [38], silica aerogel [39], konjac glucomannan-silica aerogel [40], clay/PVA aerogel [41], PVA/cellulose nanofibril aerogel [42] and hydroxyapatite nanowire aerogel [43] (Fig. S7).…”

Section: Resultsmentioning

confidence: 98%

Superhydrophobic polyvinylidene fluoride/polyimide nanofiber composite aerogels for thermal insulation under extremely humid and hot environment

et al. 2020

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Excellent thermal insulating materials are highly demanded in various applications including buildings, aerospace and sport equipment. However, in practical applications, the performance of thermal insulating materials usually deteriorates under diverse temperature and humidity conditions. Therefore, it is highly essential to construct a bulk material that exhibits outstanding thermal insulation performance under extremely humid and hot environment. In this work, we have conceived a green and effective strategy to fabricate a superhydrophobic and compressible polyvinylidene fluoride/ polyimide (PVDF/PI) nanofiber composite aerogel via electrospinning and freeze-drying technique. Interestingly, the PVDF nanofibers and PI nanofibers function as the hydrophobic fibrous framework and mechanical support skeleton, respectively, forming a robust three-dimensional framework with good mechanical flexibility. The PVDF/PI aerogel possesses outstanding superhydrophobic feature (water contact angle of 152°) and low thermal conductivity (31.0 mW m −1 K −1) at room temperature. Significantly, even at 100% relative humidity (80°C), the PVDF/PI aerogel still exhibits a low thermal conductivity of only 48.6 mW m −1 K −1 , which outperforms the majority of commercial thermal insulating materials. Therefore, the novel PVDF/PI aerogel is promising as an excellent thermal insulating material for the applications in high-temperature and humid environment.

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Section: Resultsmentioning

confidence: 98%

Superhydrophobic polyvinylidene fluoride/polyimide nanofiber composite aerogels for thermal insulation under extremely humid and hot environment

et al. 2020

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“…There are two main types of nanocellulose aerogels as adsorbent materials for oil or organic solvents. The first is the hydrophobic treatment on the surface of the nanocellulose aerogel using silane coupling agents such as trimethylchlorosilane (TMCS) and MTMS, [ 30c,60,63,70a,114 ] or various hydrophobic agents. [ 24,70b,115 ] Laitinen et al.…”

Section: Applications Of Nanocellulose Aerogelsmentioning

confidence: 99%

Recent Progress on Nanocellulose Aerogels: Preparation, Modification, Composite Fabrication, Applications

et al. 2021

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The rapid development of modern industry and excessive consumption of petroleum‐based polymers have triggered a double crisis presenting a shortage of nonrenewable resources and environmental pollution. However, this has provided an opportunity to stimulate researchers to harness native biobased materials for novel advanced materials and applications. Nanocellulose‐based aerogels, using abundant and sustainable cellulose as raw material, present a third‐generation of aerogels that combine traditional aerogels with high porosity and large specific surface area, as well as the excellent properties of cellulose itself. Currently, nanocellulose aerogels provide a highly attention‐catching platform for a wide range of functional applications in various fields, e.g., adsorption, separation, energy storage, thermal insulation, electromagnetic interference shielding, and biomedical applications. Here, the preparation methods, modification strategies, composite fabrications, and further applications of nanocellulose aerogels are summarized, with additional discussions regarding the prospects and potential challenges in future development.

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“…Increasing concerns about the use of petroleum‐based products and unsustainable fossil resources the last years has led to consider other environmentally friendly materials from renewable resources. Petroleum has a complex composition of hydrocarbons and it provides many products from fuels to feedstocks with high economic value, which makes the transition toward bio‐based materials more complicated. In addition, much more research on the production and performance of emerging biomaterials is needed before they can eventually enter the market.…”

Section: Introductionmentioning

confidence: 99%

Utilization of different tall oils for improving the water resistance of cellulosic fibers

Hosseinpourpia

Αδαμόπουλος

Parsland

2018

J of Applied Polymer Sci

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This study was conducted to assess the effect of the pulping by‐products crude tall oil (CTO), distilled tall oil (DTO), and tall oil fatty acid (TOFA) on dynamic water vapor sorption behavior, interfiber strength, and thermal stability of cellulosic paper‐sheets. The results were compared against those obtained in cellulose papers treated with the conventional petroleum‐derived hydrophobic agent hydrowax and in untreated ones. The tall oil treatments caused strong reduction in equilibrium moisture content of the paper‐sheets during adsorption and desorption runs. The same trend was noticed for the hydrowax‐treated papers, however, it was less pronounced than the CTO‐treated and DTO‐treated samples in the relative humidity range of 75–95%. The sorption hysteresis was considerably decreased after the treatments. The ultimate dry‐tensile strengths of the paper‐sheets were significantly reduced by TOFA and hydrowax treatments, while CTO and DTO showed comparable strength as that of untreated control. The ultimate wet‐strengths of the paper‐sheets were improved after the treatments. The thermal stability of the specimens was improved by the tall oil treatments, and the hydrowax‐treated samples illustrated lower degradation temperature than the untreated control. The results are promising for the use of tall oils as alternative hydrophobic agents of cellulosic fiber‐based products, such as wood panels and paper packaging. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47303.

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Oils sorption on hydrophobic nanocellulose aerogel obtained from the wood furniture industry waste

Cited by 40 publications

References 45 publications

Superhydrophobic polyvinylidene fluoride/polyimide nanofiber composite aerogels for thermal insulation under extremely humid and hot environment

Superhydrophobic polyvinylidene fluoride/polyimide nanofiber composite aerogels for thermal insulation under extremely humid and hot environment

Recent Progress on Nanocellulose Aerogels: Preparation, Modification, Composite Fabrication, Applications

Utilization of different tall oils for improving the water resistance of cellulosic fibers

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